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You may be thinking of amyl nitrates aka poppers which cause smooth muscle relaxation and are exceedingly popular for use in sex. They are...

I think sex on nos would be literally impossible. It's basically just a massive headrush, a few seconds of blacked out nothingness, then you fade...

Uhh.. it's not the same thing as poppers (amyl nitrate). Trying to fuck on nitrous would be difficult